Iron is immobile in plants. This means that plants cannot divert iron
from older leaves to new ones. Therefore, deficiency symptoms appear
first on new or young leaves. Because plants use iron to produce
chlorophyll, a lack of iron results in chlorosis, or yellowing, of the
younger leaves. Stems may also appear short and slender. If the
deficiency is severe and prolonged, each new leaf emerges lighter in
color than the preceding leaf.
When choosing an iron supplement, it is important to know
the distinction between the two forms of iron. The iron will be in one
of two oxidation states: ferrous having a +2 charge, or ferric having a
+3 charge. Ferrous iron, the preferred iron form and is soluble in water
at any pH. Ferric iron, however, is only soluble below a pH of around
5.5; but if the pH is higher than 5.5, which more than likely it will be
in a planted aquarium, the ferric iron will become insoluble and
precipitate, settling in the root zone. Once this occurs, foliar
absorbtion becomes impossible.
To overcome this precipitation, competing products employ
a chelate of ferric iron: iron-EDTA. While this does keep it soluble,
it has a couple of drawbacks with respect to foliar uptake of iron. (1)
Iron-EDTA bonding is very strong, thus very little of the iron will be
available to the plants over a given time frame and (2) Physiological
energy must be expended by the plant in order to extract the ferric iron
from EDTA-iron and then convert (reduce) it to the ferrous form. Our
approach is different in that we use a complex (not chelate) of ferrous
iron in Flourish Iron™.
Flourish Iron™ is a highly concentrated (10,000 mg/L)
ferrous iron gluconate supplement. Plants are able to much more easily
derive a benefit from Flourish Iron™ because ferrous iron gluconate is
already in the ferrous form so they do not expend energy reducing it.
Despite what other manufacturers may intimate, gluconate is not harmful
to plants or fish. In fact, ferrous gluconate is better suited to foliar
feeding than is iron-EDTA owing to the relatively weaker iron-gluconate
bonding vs. iron-EDTA bonding. In addition, ferrous gluconate has the
added bonus of being a source of carbon.
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